A Discussion on the Theory of Conjugate Reactions in the Context of Modern Ideas

Nagiev, Tofik (2020) A Discussion on the Theory of Conjugate Reactions in the Context of Modern Ideas. In: Current Perspectives on Chemical Sciences Vol. 5. B P International, pp. 39-75. ISBN 978-93-90516-13-1

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Abstract

Various types of possible interactions between reactions are discussed. Some of them are united by
the general idea of chemical reaction interference. The ideas on conjugated reactions are broadened
and the determinant formula is deduced; the coherence condition for chemical interference is
formulated and associated phase shifts are determined. It is shown how interaction between reactions
may be qualitatively and quantitatively assessed and kinetic analysis of complex reactions with underresearched
mechanisms may be performed with simultaneous consideration of the stationary
concentration method. Using particular examples, interference of hydrogen peroxide dissociation and
oxidation of substrates is considered. The ensemble of reactions is self-organized through the
intermediary of general highly active substances. These processes may be accelerated and
effectively implemented with the help of catalysts similar to processes, which take part in the living
systems. Self-organization of an ensemble of reactions capable of being intensified or weakened and,
therefore, inducing chemical interference, may be suggested as the basis for the principle of
organization of many enzymatic ensembles.

Item Type: Book Section
Subjects: Apsci Archives > Chemical Science
Depositing User: Unnamed user with email support@apsciarchives.com
Date Deposited: 02 Dec 2023 05:42
Last Modified: 02 Dec 2023 05:42
URI: http://eprints.go2submission.com/id/eprint/2310

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